岩溶水硝酸盐污染原位修复试验     

叶进霞  夏春英  卜鸿志 《中国岩溶》2020,39(2):173-179

岩溶含水层的极不均一性特征使岩溶水溶质运移受构造、裂隙空间及其发育方向控制；因环境条件复杂，开展岩溶水污染原位修复技术难度较大，截止目前，国内尚未系统地开展岩溶含水层水污染原位修复研究工作。文章选择鲁中南山区典型岩溶发育及硝酸盐污染地段，施工组合钻孔建设修复试验工程，采用“乙醇+葡萄糖”液态碳源和“聚乙烯醇+淀粉颗粒”固态反应器分别进行岩溶水硝酸盐污染原位修复试验。结果表明:浓度500 mg?L－1、1 000 mg?L－1的“乙醇+葡萄糖”反硝化溶液对硝酸盐浓度的降解率分别为6.45 %和21.52 %；单位长度组成材料“聚乙烯醇3 kg+淀粉颗粒3 kg”、“聚乙烯醇2 kg+淀粉颗粒4 kg”的两种反硝化固态反应器对硝酸盐浓度的降解率分为33.91%和34.96%。试验证明在裂隙型岩溶地区采用孔组方案进行地下水污染原位修复技术可行、且能取得较显著效果。修复工程布设方式和试验成果对类似地区开展岩溶地下水污染原位修复具一定借鉴意义。   相似文献   

Volatile element chemistry during accretion of the earth     

《Chemie der Erde / Geochemistry》2020,80(1):125594

We review some issues relevant to volatile element chemistry during accretion of the Earth with an emphasis on historical development of ideas during the past century and on issues we think are important. These ideas and issues include the following: (1) whether or not the Earth accreted hot and the geochemical evidence for high temperatures during its formation, (2) some chemical consequences of the Earth’s formation before dissipation of solar nebular gas, (3) the building blocks of the Earth, (4) the composition of the Earth and its lithophile volatility trend, (5) chemistry of silicate vapor and steam atmospheres during Earth’s formation, (6) vapor - melt partitioning and possible loss of volatile elements, (7) insights from hot rocky extrasolar planets. We include tabulated chemical kinetic data for high-temperature elementary reactions in silicate vapor and steam atmospheres. We finish with a summary of the known and unknown issues along with suggestions for future work.  相似文献   

Detection of coffee berry necrosis by digital image processing of landsat 8 oli satellite imagery     

《International Journal of Applied Earth Observation and Geoinformation》2020

Coffee berry necrosis is a fungal disease that, at a high level, significantly affects coffee productivity. With the advent of surface mapping satellites, it was possible to obtain information about the spectral signature of the crop on a time scale pertinent to the monitoring and detection of plant phenological changes. The objective of this paper was to define the best machine learning algorithm that is able to classify the incidence CBN as a function of Landsat 8 OLI images in different atmospheric correction methods. Landsat 8 OLI images were acquired at the dates closest to sampling anthracnose field data at three times corresponding to grain filling period and were submitted to atmospheric corrections by DOS, ATCOR, and 6SV methods. The images classified by the algorithms of machine learning, Random Forest, Multilayer Perceptron and Naive Bayes were tested 30 times in random sampling. Given the overall accuracy of each test, the algorithms were evaluated using the Friedman and Nemenyi tests to identify the statistical difference in the treatments. The obtained results indicated that the overall accuracy and the balanced accuracy index were on an average around 0.55 and 0.45, respectively, for the Naive Bayes and Multilayer Perceptron algorithms in the ATCOR atmospheric correction. According to the Friedman and Nemenyi tests, both algorithms were defined as the best classifiers. These results demonstrate that Landsat 8 OLI images were able to identify an incidence of the coffee berry necrosis by means of machine learning techniques, a fact that cannot be observed by the Pearson correlation.  相似文献   

Groundwater contaminant source identification based on iterative local update ensemble smoother          下载免费PDF全文

YANG Ai-lin  JIANG Si-min  LIU Jin-bing  JIANG Qian-yun  ZHOU Ting  ZHANG Wen 《地下水科学与工程》2020,8(1):1-9

Identification of the location and intensity of groundwater pollution source contributes to the effect of pollution remediation, and is called groundwater contaminant source identifcation. This is a kind of typical groundwater inverse problem, and the solution is usually ill-posed. Especially considering the spatial variability of hydraulic conductivity field, the identification process is more challenging. In this paper, the solution framework of groundwater contaminant source identification is composed with groundwater pollutant transport model (MT3DMS) and a data assimilation method (Iterative local update ensemble smoother, ILUES). In addition, Karhunen-Loève expansion technique is adopted as a PCA method to realize dimension reduction. In practical problems, the geostatistical method is usually used to characterize the hydraulic conductivity feld, and only the contaminant source information is inversely calculated in the identifcation process. In this study, the identification of contaminant source information under Kriging K-field is compared with simultaneous identification of source information and K-field. The results indicate that it is necessary to carry out simultaneous identification under heterogeneous site, and ILUES has good performance in solving high-dimensional parameter inversion problems.  相似文献   

Geographical information system-based groundwater quality index assessment of northern part of Kolkata,India for drinking purpose     

Suranjana Banerji  Deblina Mitra 《国际地球制图》2019,34(9):943-958

Groundwater is a resource under stress. In both developed and developing countries, it has been found that increasing human influence has led to the contamination of the groundwater resource. To understand the magnitude of this problem, a study was conducted in 58 wards within Northern part of Kolkata, India, where water samples from tube wells were collected and analysed on essential drinking water quality parameters, prescribed by WHO. Using Principal component analysis, and Water quality index mapping, the aforementioned results have been interpreted. This has helped to depict that not only is the groundwater unsuitable for drinking, but that the parametric values have a tendency to increase abruptly within the shortest of ranges, indicating urban pollution as the root cause of contamination. This paper shall thus discuss the spatial change in groundwater quality in northern Kolkata and suggest measures which might be implemented to secure a sustainable future for the city.  相似文献   

中国东北新生代火山区CO_2释放规模与成因     

赵文斌  郭正府  刘嘉麒  张茂亮  孙玉涛  雷鸣  马琳  李菊景 《岩石学报》2021,37(4):1255-1269

板片俯冲过程将地表碳带入地球内部,火山作用将深部碳输送至地球外部圈层,两者构成了地球深部碳循环的主要方式,进而影响了地史时期的气候变化。我国东北新生代火山活动被认为是太平洋板片深俯冲作用的产物,板片俯冲导致岩浆源区强烈的碳酸盐组分交代作用,进而使东北亚上地幔成为一个新生代时期的巨型深部碳库,它的活动和释放将会对全球的气候与环境变化造成重要影响。然而,有关该深部碳库向当今大气圈输送CO_2气体的规模及其演化过程尚不清楚,从而影响了进一步定量评估该碳库在全球变化研究中的地位和作用。针对上述科学问题,本文对我国东北长白山、五大连池和阿尔山火山释放CO_2气体的规模与成因进行了研究。结果表明,东北新生代火山区的土壤CO_2释放通量介于9.6～41.2g·m~(-2)·d~(-1)之间,每年向当今大气圈释放CO_2气体约为2.1Mt(其中,长白山火山区为0.94Mt,五大连池火山区为1.2Mt)。气体地球化学研究证实,长白山与五大连池火山气体均起源于太平洋板片深俯冲环境;但是,与长白山相比,五大连池火山气体具有较高比例壳源组分贡献。阿尔山火山气体的成分与长白山和五大连池火山区存在着明显的差异,它们以N_2为主( 95%),并且其δ~(15)N_(N_2)值高于空气值(1.3‰～1.9‰),~3He/~4He比值较低(0.14～0.18R_A),δ~(13)C_(CO_2)较轻(-13.7‰～-6.2‰),表明壳源富氮有机沉积物的贡献占比较大的比例。上述特征进一步表明,阿尔山火山气体在上升经过地下水时可能滞留了较长时间,混染了大量的陆壳组分,其源区并未受到太平洋板片俯冲物质的显著影响。  相似文献   

由非季风区向季风区过渡过程中大气边界层结构的变化分析   总被引：2，自引：0，他引：2  

乔梁  张强  岳平  金红梅 《大气科学》2019,43(2):251-265

利用中国西北中部具有代表性的非季风区、夏季风影响过渡区和季风区的7个高空站的2013年夏季晴天07时、13时、19时（北京时）的大气边界层资料,通过分析大气边界层位温、比湿、风速的垂直结构,发现大气边界层结构及厚度在不同区域的分布特征:稳定边界层厚度、残余层顶高度和对流边界层厚度从非季风区、夏季风影响过渡区至季风区出现阶梯性大幅降低,从非季风区至夏季风影响过渡区,以及从夏季风影响过渡区至季风区,对流边界层厚度降幅依次为25.6%和81.8%,稳定边界层厚度降幅依次为58.3%和41.8%;在稳定边界层条件下,可观察到低空急流的存在,非季风区低空急流出现高度明显高于夏季风影响过渡区和季风区,且非季风区的低空急流风速也明显大于夏季风影响过渡区和季风区。通过分析与大气边界层发展最为密切的陆面热力因素在不同气候区的分布,净辐射值、日地-气温差最大值以及感热通量值在非季风区大于夏季风影响过渡区和季风区,从陆面热力过程为非季风区大气边界层厚度大于夏季风影响过渡区和季风区提供了理论依据。  相似文献   

华北雨季开始早晚与大气环流和海表温度异常的关系   总被引：2，自引：0，他引：2  

于晓澄  赵俊虎  杨柳  支蓉  封国林 《大气科学》2019,43(1):107-118

本文利用国家气候中心的1961~2016年华北雨季监测资料、美国国家环境预报中心/大气研究中心（NCEP/NCAR）的大气再分析资料、NOAA海表温度资料,分析了华北雨季开始早晚的气候特征,然后利用合成分析、回归分析等方法,研究了华北雨季开始早晚与大气环流系统和关键区域海表温度的关系。结果表明,56 a来华北雨季开始最早在7月6日,最晚在8月10日,1961~2016年华北雨季开始平均日期是7月18日。华北雨季开始时间具有显著的年际变化,但雨季发生早晚的长期变化趋势不太明显。华北雨季开始早晚与西太平洋副热带高压（简称副高）、东亚副热带西风急流、东亚夏季风等环流系统的活动关系密切,当对流层高层副热带西风急流建立偏早偏强,中层西太平洋副高第二次北跳偏早,低层东亚夏季风北进提前时,华北雨季开始偏早,反之华北雨季开始偏晚。华北雨季开始早晚与春、夏季热带印度洋、赤道中东太平洋海表温度关系显著且稳定,当Ni?o3.4指数和热带印度洋全区海表温度一致模态（IOBW）为正值时,贝加尔湖大陆高压偏强,副高偏强偏南,东亚夏季风偏弱,导致华北雨季开始偏晚;当海表温度指数为负值时,则华北雨季开始偏早。  相似文献   

2015年济南地区雾霾天气过程大气物理量特征初步分析          下载免费PDF全文

崔雅琴  张佃国  王洪  刘泉  张骞  张洪生 《大气科学》2019,43(4):705-718

文中对比分析了2015年29个雾、霾及雾霾混合天气过程中,章丘探空站L波段探空雷达和山东省气象局院内德国14通道地基微波辐射计观测的温度资料。对观测数据实施了质量控制,检验了精度和可信度,统计分析了宏观物理参量特征和日变化规律。针对雾、霾及雾霾天气过程各选取了一个个例进行分析,分析了大气中PM_2.5、PM₁₀、SO₂、NO₂、O₃、CO含量的变化情况,分析了相对湿度、液态水路径和综合水汽含量等的变化情况。结果表明:两种观测数据一致性较好,拟合优度高于0.97;贴地逆温层存在一定的季节变化,悬垂逆温层存在一定的差异,逆温层的变化、污染参量变化与雾霾的形成有密切关系;不同天气背景对大气物理参量有较大的影响,PM₁₀、AQI（空气质量指数）和CO均在相同时间段出现峰值,有明显的起伏;CO峰值雾霾天气中尤为明显,由早到晚随时间峰值逐渐增大,雾天和霾天峰值较小,雾霾天气明显大于雾天或霾天。  相似文献   

六盘山区夏秋季大气水汽和液态水特征初步分析     

田磊  桑建人  姚展予  常倬林  单新兰  曹宁  孙艳桥 《气象与环境学报》2019,35(6):28-37

六盘山区是中国典型的农牧交错带和生态脆弱带,也是黄土高原重要的水源涵养地、生态保护区及国家级扶贫开发区。利用2017年6-11月隆德气象站地基多通道微波辐射计资料,结合同期平凉探空站及隆德地面降水等观测资料,分析了六盘山区夏秋季大气水汽、液态水变化特征。结果表明：六盘山区夏秋季在降水天气背景下,大气水汽含量和液态水含量均较高,分别为无降水天气背景下的1.4倍和7.0倍;降水天气背景下水汽在5000 m以下有明显的增加,且在此高度范围内的水汽密度随高度的递减率比无降水天气背景下明显偏小;各高度层的液态水相比无降水天气背景下均有明显增大,除6月外,主峰值均出现在0℃层高度层以下。六盘山区夏秋季各月中,6-9月。大气水汽含量高值区均出现在正午到傍晚时段,低值区均出现在日出前后;液态水含量在日出前、午后及傍晚分别出现峰值,最明显的峰值出现在午后。对一次对流性降水天气过程分析后发现,降水发生前40 min大气水汽含量和液态水含量出现两次明显的跃增,水汽向上输送不断加强,2500-7500 m高度的相对湿度明显增大。  相似文献